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The adhesion of paint coatings:
The adhesion of paint coatings:
From the mechanisms of protection against corrosion coatings of paint, good adhesion to the underlying material is obviously very desirable. The adhesion is thought to be a combination of mechanical effects, chemical and physical (the relative importance of each of these has varied somewhat over the years).These bonding effects are all based on intimate contact between the underlying material and lining up across the molecular level. Effective wetting of the material to be coated is important. Note that, with all other things being equal, a larger surface area offers more mechanical and / or chemical and / or physical anchor (bonding) sites.Mechanical interlock: "Lock and key" effect, the mechanical anchoring on rough and porous surfaces. Surface roughness increases the effective surface area of ​​contact. The absorption of the coating liquid is relevant in the substrate (analogy with a liquid absorbed by a porous sponge).Adsorption effects "chemical" binding from strong chemical bonds (chemisorption) through the bonding interface to weak forces of van der Waals * (physisorption) that are based on temporary permanent dipole interactions.Electrostatic double layer of opposite charges created at the bonding interface (a simple analogy is that of a charged capacitor).Distribution: applicable to polymeric coatings on polymeric substrates and the substrate being permeable coating, diffusion through the link interface to produce a tangle of molecules of polymer chain. * These van der Waals forces are now believed to play a major role in the remarkable feats of grip of geckos, billions of microscopic keratin hair on the surfaces of their feet to facilitate such a connection dry. (Editor's note: there goes the theory grandmother sucker ...)
Chemisorption: chemical adsorption - by valence forces of the same nature as found in the formation of chemical compounds.Physisorption: physical adsorption - by intermolecular forces (van der Waals) that do not involve a significant change in patterns of orbital electrons.It was noted that a clear distinction between chemisorption and physisorption is not always possible, as is the case for the chemical and physical interactions in general.(Reference:. IUPAC, Physical Chemistry Division, Manual of symbols and terminology for physicochemical quantities of DH Everett)Advertising design and production, decoration & events.
  
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